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21.
We report a new hyperchaotic attractor coined from the chaotic Lü system by using a state feedback controller. Theoretical analyses and simulation experiments are conducted to investigate the dynamical behaviour of the proposed hyperchaotic system 相似文献
22.
《中国化学快报》2020,31(6):1654-1659
The carbon quantum dots(CQDs) and their functionalized materials are promising in biomedical field because of their unique properties;meanwhile,a growing concern has been raised about the potential toxicity of these modified materials in biosystem.In this study,we synthesized original CQDs and two common functionalized CQDs including N-doped CQDs(NCQDs) and folic acid-modified CQDs(FACQDs),and compared the toxicity and biocompatibility with each other in vitro and in vivo.L929,C6 and normal cell MDCK were selected to detect the adverse reaction of these materials in vitro.No acute toxicity or obvious changes were noted from in vitro cytotoxicity studies with the dose of these CQD materials increasing to a high concentration at 1 mg/mL.Among these materials,the FA-CQDs show a much lower toxicity.Moreover,in vivo toxicity studies were performed on the nude mice for 15 days.The experimental animals in 10 or 15 mg/kg groups were similar with animals treated by phosphate buffer solution(PBS) after 15 days.The results of the multifa rious biochemical parameters also suggest that the functionalized products of CQDs do not influence the biological indicators at feasible concentration.Our findings in vitro and in vivo through toxicity tests demonstrate that CQDs and their modified materials are safe for future biological applications. 相似文献
23.
A. D. Wang C. F. Bi Y. H. Fan Y. N. Zou J. K. Xu Y. H. Kan 《Russian Journal of Coordination Chemistry》2008,34(7):475-479
The structure and coordination environment of unusually double-stranded helix of complex [Zn(C8H7O3)2(H2O)2] are studied experimentally and by the density functional theory (DFT) method. The Zn2+ ion coordinates six oxygen atoms of deprotonated vanillin and water molecules forming an octahedron. The intermolecular hydrogen
bonds and π interactions of the vanillin fragments contributed to the formation of the double-stranded helical supramolecular
structure in the crystal. Counterpoise geometric parameters of the calculation agree with the crystal structure determined
by experiment. The stabilization energy between the donor and acceptor obtained from an analysis of natural bond orbitals
of the indicated six ligand oxygen atoms act as electron donor to Zn2+ ion. The results of the density functional theory on the complex demonstrate that the different coordinated oxygen atoms,
which have different chemical environment, distort the coordination octahedron.
The text was submitted by the authors in English. 相似文献
24.
《Particuology》2015
We present a rigorous theoretical model for the influence of the aperture in interferometric out-of-focus imaging. We investigate the role of this effect on the properties of speckle-like patterns generated by irregular, rough particles. Finally, we determine the conditions under which these patterns are no longer representative of particle size but of the aperture itself and the defocus parameter. 相似文献
25.
Pu Su Zhao Rong Qing Li Xiao Jun Sun Huan Mei Guo Fang Fang Jian 《Structural chemistry》2009,20(3):443-451
Two 2-pyrazoline derivatives of 1-phenyl-3-(4-chlorophenyl)-5-(2-chlorophenyl)-2-pyrazoline (1) and 1-phenyl-3-(4-methylphenyl)-5-(2-chlorophenyl)-2-pyrazoline (2) have been synthesized and characterized by elemental analysis, IR, UV–Vis, and fluorescence spectra. The crystal structure
of 2 has been determined by X-ray single crystal diffraction. For the two compounds, density functional theory (DFT) calculations
of the structures and natural population atomic charge analysis have been performed at B3LYP/6-311G** level of theory. By
using TD-DFT method, electron spectra of 1 and 2 have been predicted, which are in good agreement with the experimental ones. Comparative studies on 1 and 2 indicate that the change of substituted groups in 3-phenyl ring of pyrazoline ring will change the peak intensity and peak
locations both in electron spectra and fluorescence spectra. 相似文献
26.
具偏差变元的高阶泛函微分方程的周期解存在性问题 总被引:1,自引:0,他引:1
利用Fourier级数理论,伯努利数理论和重合度理论研究了一类具偏差变元的高阶泛函微分方程x(m)(t)+(m-1)∑(i=1)aix(i)(t)+f(x(t))+β(t)g(x(t-T(t)))=p(t)的周期解问题,得到了周期解存在的充分条件,有意义的是函数β(t)可变号. 相似文献
27.
采用溶胶凝胶法成功制备了SrTiO3∶Pr3+、SrTiO3∶Pr3+, Mg2+ 及SrTiO3∶Pr3+, Al3+荧光粉.通过XRD、PL谱及第一性原理计算对样品的晶体结构、光谱特性及发光增强机制进行了研究.研究结果表明:共掺杂后,SrTiO3∶Pr3+荧光粉为单一组成的SrTiO3立方相,主发射锋位于617 nm, 对应于Pr3+离子的1D2→3H4跃迁发射.SrTiO3∶Pr3+, Mg2+ 及SrTiO3∶Pr3+, Al3+荧光粉的发光强度分别是SrTiO3∶Pr3+荧光粉发光强度的7倍和2倍,但主要发光机制没有改变.Mulliken布局分析表明,Mg2+、Al3+离子的掺入使SrTiO3∶Pr3+荧光粉中Ti-O及Pr-O键的化学键增强、键长变短,SrTiO3∶Pr3+基质向Pr3+离子发光中心的能量传递效率提高,导致SrTiO3∶Pr3+, Mg2+ 及SrTiO3∶Pr3+, Al3+荧光粉的发光效率提高. 相似文献
28.
以氯乙酰氯和对碘苯胺为原料,经酰化合成了4-碘-氯乙酰苯胺,接着与1-甲基咪唑反应得到氯化1-甲基-3-(4-碘苯氨基甲酰甲基)咪唑钅翁,随后在水溶液中发生阴离子交换,合成了1-甲基-3-(4-碘苯氨基甲酰甲基)咪唑四氟硼酸盐;四氟硼酸盐在过氧化氢/三氟乙酸酐体系中氧化得到一种新的离子液体负载的双(三氟乙酰氧基)碘苯试剂1-甲基-3-[4-双(三氟乙酰氧基)碘苯氨基甲酰甲基]咪唑四氟硼酸盐。反应总收率62.3%。试剂没有吸湿性,在空气中长期放置不变质。化学结构用IR、1H NMR、13C NMR、19F NMR和元素分析表征。 相似文献
29.
30.
Non-Gaussianity and decoherence of generalized photon-added coherent state as a Hermite-excited coherent state 下载免费PDF全文
Generalized photon-added coherent state (GPACS) is obtained by repeatedly acting the combination of Bose creation and annihilation operations on the coherent state. It is found that GPACS can be regarded as a Hermite-excited coherent state due to its normalization factor related to a Hermite polynomial. In addition, we adopt the Hilbert-Schmidt distance to quantify the non-Gaussian character of GPACS and discuss the decoherence of GPACS in dissipative channel by studying the loss of nonclassicality in reference of the negativity of Wigner function. 相似文献